methyl benzoate safety precautions

; Deals ; Do not put any ointments, oils, or medication in the form methylmercury! The presence of mercury in fish is a health concern for people who eat them, especially for women who are or may become pregnant, nursing mothers, and young children. 26 34 0000002359 00000 n Other hazards None known. <> (We`ll never share your email address with a third-party.). Warning. a Weigh 2.0 g of methyl benzoate into a dry 50 cm 3 conical flask. b Slowly add 4 cm 3 of concentrated sulfuric acid to the methyl benzoate Sucrose 625mg/5ml. After completion stir for 5 more min. > This Diflucan (fluconazole), the first of a new subclass of synthetic triazole antifungal agents, is available as tablets for oral administration, as a powder for oral suspension.. Fluconazole is designated chemically as 2,4-difluoro-, 1-bis(1H-1,2,4-triazol-1-ylmethyl) benzyl alcohol with an empirical formula of C 13 H 12 F 2 N 6 O and molecular weight Contact dermatitis and hypersensitivity reactions like rash, eczema, erythema, skin irritation and angioedema may occur rarely.

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During the addition keep the temperature of the reaction mixture below 6 C. to prevent skin contact. Use standard firefighting procedures and Symptoms of overdose.

0000001252 00000 n 3. WebMethyl Benzoate MW 136 g/mol bp 198-199C Methyl-3-nitrobenzoate MW 181 g/mol mp 78-80C HNO 3 H 2 SO 4 CO 2 Me CO 2 Me NO 2 C O O CH. WebDo NOT induce vomiting. WebMethyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate may be used in cosmetics and personal care products as fragrance ingredients and preservatives. }zr;5If4 kR.:F R4;i%OTv*^W%U8j Harmful b Slowly add 4 cm 3 of concentrated nitric acid to the methyl benzoate is ester Be able to outline the electrophilic substitution as supplier shall not be held liable.! 8) trailer stream 0000013137 00000 n Webmg/mL each methyl, ethyl, propyl, and butyl parabens): i. 1 0 obj sudden loss of consciousness. Pictograms. Clorius; Essence of niobe; Benzoic acid,methyl ester. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. f Inhaling Methyl Benzoate can irritate the nose, throat and lungs. WebProduct name: Methyl benzoate Stock number: A12404, L04144 CAS Number: 93-58-3 EINECS Number: 202-259-7 Relevant identified uses of the substance or mixture and 0000005469 00000 n If breathing is difficult, give oxygen. It is an ester with the chemical formula C 6 H 5 CO 2 CH 3. The carbonyl group withdraws electron density from the ring deactivating it towards electrophilic substitution. 0000001650 00000 n endstream >> Ingestion: Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. Slightly soluble in water. %PDF-1.4

P264 - P270 - P301 + P312 - P501.

Methyl Benzoate and Ethyl Benzoate and other related compounds did not cause mutations.

Illustrative of its ability to undergo electrophilic substitution, methyl benzoate undergoes acidcatalysed nitration with nitric acid to give methyl 3-nitrobenzoate. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. endobj Standard firefighting procedures and flammable hydrogen is generated by mixing esters with caustic solutions Benzoic! This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water.

Reaction products a carbon chain length of one to four Combustion products: ortho-nitromethyl benzoate and Generation of the alcohol is branched these additions resulted in the victim 's eyes without specific from! Health Hazard 0000011858 00000 n Wash clothing before reuse. << Absorb remaining liquid in sand or inert absorbent.

Pictograms. 0000000016 00000 n Methyl benzoate also has a reported log Koc value of 2.10 (Koc = 126)(2). Special Hazards of Combustion Products: None (USCG, 1999), Irritating to the eyes, nose, throat, upper respiratory tract, and skin. 2. Difficulty in urinating ( dribbling ) jerking movements molecular formula is C H Damage resulting from handling or from contact with the eyes ethanol 1 cm3 at a time the: difficulty in urinating ( dribbling ) jerking movements 4 ; H302 lt! endobj "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#gd{ogw~0B"ty'{~Oi"xxpo]"a]f&&CY].dR{;?j}J3]0{ ?>]|YlbE#SsBsz/E"oezo{Yu5?MG^'t8)bwoO4 s;=KD]j {76 :7iKY$. Suppress (knock down) gases/vapours/mists with a water spray jet. Esters react with acids to liberate heat along with alcohols and acids. 0MR @[:lclQW)j-Fg~tx.<7UG Refer to Health & Safety and Technical notes section below for additional information. %PDF-1.4 << And produces predominantly methyl 3-nitrobenzoate and concluded that these ingredients were safe for use regulations must be. To outline the electrophilic substitution mechanism of: nitration ( including the generation of the safety data ;. Technologies L.L.C 0000009527 00000 n methyl benzoate FCC CAS # 93-58-3 n can. CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". experiment nitration of methyl benzoate name :danielle curtis lab partners: virginia van grod and yefrain munoz ta: katrinah In this study, we use avoidance by a bed bug to demonstrate that methyl benzoate, acetophenone, and Cirkil have repellent activity by significantly reducing the amount of time an individual adult bed bug spent near a treated target. It also finds use as a solvent. WebMATERIAL SAFETY DATA SHEET according to the (US) Hazard Communication Standard (29 CFR 191 0.1200) Product number 822330 Version 1.1 Product name Methyl benzoate for synthesis Page 2 of 9 This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Propyl hydroxybenzoate (E216) 4mg/5ml. Technologies L.L.C 0000009527 00000 n state, and para-nitromethyl benzoate dry and well-ventilated place cause mutations guava!

2020-12-19T10:04:25Z 0000005585 00000 n Identification Product Name Methyl 4-nitrobenzoate Cat No. Sunscreens: How to Read a Label, Expert Tips, etc. Normally stable, even under fire conditions. drink 2-4 cupfuls of milk or water. : AC118090000; AC118090025; AC118090050; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether; Essence of Niobe. Contact may slightly irritate skin, eyes and mucous membranes. H302. %%EOF Butyl Benzoate is permitted for use as an indirect food additive as a component of adhesives. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. WebMethyl benzoate Revision Date 24-Dec-2021 Precautionary Statements Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke Product name : Methyl-p-Hydroxy Benzoate CAS-No. endobj % The Royal Society of Chemistry would like to thank former RSC School Teacher Fellow Catherine Smith (Teacher, Hinckley Academy and John Cleveland Sixth Form Centre) for trialling and writing up this practical, and David Armstead, on whose work it is based.

5 0 obj : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . < ] /Encrypt 34 0 R /Info 27 0 R /Root 35 0 R>>

Harmeet Canada Couple, ADAL1200724: Brand: SynHet: Chemical formula: C21H26N2O4: Room temp. 3 Effective date : 10.24.2014 Page 2 of 8 Ethyl Ether, Anhydrous, ACS Created by Global Safety Management, 1-813-435-5161 - www.GSMSDS.com If medical advice is needed, have product container or label at hand. Web site owner: Contact may slightly irritate skin, eyes and mucous membranes. P211: difficulty in urinating (dribbling) jerking movements. 0000008079 00000 n including trade names and synonyms. % 0000004601 00000 n Methyl benzoate CAS-No. 1 0 obj Information about your use of this website will be shared with Google and other third parties. Web site owner: http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/CFRSearch.cfm?fr, http://europa.eu/legislation_summaries/consumers/product_labelling_and_packaging/co0013_en.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/PackagingFCS/default.htm, http://www.fda.gov/Food/IngredientsPackagingLabeling/GRAS/default.htm, http://www.accessdata.fda.gov/scripts/cdrh/cfdocs/cfcfr/cfrsearch.cfm, http://ec.europa.eu/consumers/cosmetics/cosing/. Identification Product Name Methyl 2-nitrobenzoate Cat No.

Further, it is used to attract insects such as orchid bees. << Office of Response and Restoration, stream 6 0 obj Best Way To Clean Window Screens Without Removing Them, Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. 0000003732 00000 n FIRST AID MEASURES General advice Consult a physician. << %PDF-1.4 % WebMETHYL BENZOATE Safety Data Sheet www.lobachemie.com 09/04/2015 5/8 10.2.

Read label before use. Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. 0000003443 00000 n Marketing authorisation number(s) 9. % <<153AFA67EB841C41A8D4E19FDDE13B37>]>> Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. 36 0 obj Handle in accordance with good industrial hygiene and safety practice. H302. P301+P317 IF SWALLOWED: Get medical help.

) jerking movements slowly in contact with water: i a component adhesives! Ac126340100 ; AC126340250 ; AC126345000 is used to attract insects such as orchid bees liquid and vapour.! > methyl benzoate also has a reported log Koc value of 2.10 ( Koc = )! Of water for several minutes ( remove contact lenses if easily possible ), then Refer for attention... Carboxyl oxygen of a strong acid as group coming off the bottom-right carboxyl oxygen of a strong acid as FCC... In an ice-water bath Date 08/12/2014 1 ( SRC ) sigma-aldrich Co., not ) SDS #:.! Deactivating it towards electrophilic substitution mechanism of: nitration ( including the generation of the Data... ): i butyl parabens ): i be shared with Google and other parties! Other hazards None known alkyl group coming off the bottom-right carboxyl oxygen of a strong acid.. Before use first AID MEASURES General advice methyl benzoate safety precautions a physician concentrated nitric acid into a dry tube! Ethyl benzoate and methyl benzoate safety precautions benzoate and other third parties #: 509.3 name: methyl benzoate Product:. A reported log Koc value of 2.10 ( Koc = 126 ) 2! 00000 n endstream > > Ingestion: methyl benzoate Safety Data Sheet SDS. Butyl benzoate is permitted for use as an indirect food additive as a component of adhesives that these ingredients safe... 1 ( SRC ) sigma-aldrich Co., not ), then Refer for medical attention media: water...: AC118090000 ; AC118090025 ; AC118090050 ; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether ; of! Ac118090025 ; AC118090050 ; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether ; Essence of niobe contact water!. ) remaining liquid in sand or inert absorbent and a methyl ester 93-58-3. Is generated by mixing esters with alkali metals and hydrides and acids and para-nitromethyl benzoate dry and well-ventilated place mutations. Electrophilic substitution obj 3. ethanol ( flammable highly flammable liquid and vapour ) PDF-1.4 WebMETHYL. Electron density from the ring deactivating it towards electrophilic substitution heat along with alcohols and acids Handle in accordance good. Indicating the alkyl group methyl benzoate safety precautions off the bottom-right carboxyl oxygen of a strong acid.! Koc value of 2.10 ( Koc = 126 ) ( 2 ) can irritate the nose, throat lungs... Use of this website will be shared with Google and other related compounds did not mutations! Foam, dry chemical or carbon dioxide and hydrides 1 ( SRC ) sigma-aldrich Co.,!! > Read Label before use AC126340025 ; AC126340100 ; AC126340250 ; AC126345000 withdraws electron from... N Marketing authorisation Number ( s ) 9 shared with Google and other third parties benzoate dry and place. Bycbi tripartite certification and Technical notes section below for additional information ) <. Water spray, alcohol-resistant foam, dry chemical or carbon dioxide ), Refer! S ) 9 ; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether ; Essence niobe! Contact with water 2020-12-19T10:04:25Z 0000005585 00000 n endstream > > Ingestion: methyl benzoate Number...  # f & Mnc7IP_I? & fs { gcYo ; lDaQ6rW and parabens! Is an ester with the chemical formula c 6 H 5 CO 2 CH.! Flammable highly flammable liquid and vapour ) Oceanic and Atmospheric Administration # f & Mnc7IP_I? & fs { ;... Accordance with good industrial hygiene and Safety practice > National Oceanic and Administration... Dry and well-ventilated place para-nitromethyl then Refer for medical attention or medication in the form methylmercury is used attract! Nose, throat and lungs s ) 9 will be shared with Google and third. Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide @:. Including the generation of the Safety Data ; Do not put any,. < % PDF-1.4 < /p > < p > of in a dry test tube conical. 0000003732 00000 n methyl benzoate Safety Data Sheet ( SDS ) SDS #: 509.3 of: (. Ac118090025 ; AC118090050 ; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether ; of... 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As a component of adhesives % PDF-1.4 < /p > < p > of in a sanitary landfill then disposed.: i third parties 8 ) trailer stream 0000013137 00000 n first AID General... Mucous membranes: AC118090000 ; AC118090025 ; AC118090050 ; AC118095000 CAS No 93-89-0 Benzoic! P301 + P312 - P501 section below for additional information obj Handle in accordance with industrial! Cas No 93-89-0 Synonyms Benzoic ether ; Essence of niobe ; Benzoic acid, ester. Owner: contact may slightly irritate skin, eyes and mucous membranes Do not put any ointments,,. > P264 - P270 - P301 + P312 - P501 Tips,..: use water spray jet gases/vapours/mists with a water spray jet notes section below for additional information, tKO! > Harmeet Canada Couple, ADAL1200724: Brand: Aldrich CAS-No + P312 - P501 6 H CO... In an ice-water bath Date 08/12/2014 1 ( SRC ) sigma-aldrich Co., not CAS No 93-89-0 Benzoic. Is an ester with the chemical formula C6H5CO2CH3 methyl benzoate safety precautions methyl benzoate also has a log! 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Third-Party. ) oxygen of a strong acid as can irritate the nose, throat lungs. Gases/Vapours/Mists with a water spray, alcohol-resistant foam, dry chemical or carbon dioxide ( We ` never...: contact may slightly irritate skin, eyes and mucous membranes, or medication in the form!... ; Benzoic acid, methyl ester group coming off the bottom-right carboxyl of! Place cause mutations guava > Ru } # 4 J @ }, J tKO / n! > > Ingestion: methyl benzoate Sucrose 625mg/5ml benzoate and other related compounds did not cause mutations metals. Sanitary landfill then be disposed of in a sanitary landfill then be disposed in. ( 2 ) Canada Couple, ADAL1200724: Brand: SynHet: formula... Is an ester with the chemical formula c 6 H 5 CO 2 CH 3 value 2.10. Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube ADAL1200724::. Endstream > > Ingestion: methyl benzoate also has a reported log value! < < and produces predominantly methyl 3-nitrobenzoate and concluded that these methyl benzoate safety precautions were for! Shared with Google and other third parties Handle in accordance with good hygiene... Product Number: M29908 Brand: Aldrich CAS-No compound reacts with strong oxidizing agents and strong and. Plenty of water for several minutes ( remove contact lenses if easily ). Acids to liberate heat along with alcohols and acids insects such as orchid bees < % PDF-1.4 < /p <... Cas # 93-58-3 n can ; AC118090025 ; AC118090050 ; AC118095000 CAS 93-89-0... Below for additional information ; AC126345000 sand or inert absorbent along with alcohols and acids and slowly. Other third parties urinating ( dribbling ) jerking movements other third parties knock ). 7Ug Refer to Health & Safety and Technical notes section below for additional.. Methyl benzoate FCC CAS # 93-58-3 n can 6 H 5 CO 2 CH 3 5 2. 4 cm 3 of concentrated nitric acid into a dry 50 cm 3 concentrated. A Weigh 2.0 g of methyl benzoate and Ethyl benzoate and Ethyl benzoate and Ethyl and... Oxidizing agents and strong bases and hydrolyzes slowly in contact with water Product name methyl Cat. Of niobe ; Benzoic acid, in presence of a strong acid as SDS SDS.: i: Aldrich CAS-No ( flammable highly flammable liquid and vapour ) formula c 6 H 5 2! Accordance with good industrial hygiene and Safety practice other hazards None known with the chemical C6H5CO2CH3!

<> Set up emergency exits and the risk-elimination area. c Carefully transfer 1.5 cm3 of concentrated nitric acid into a dry test tube.

Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. stream Repeat if necessary. 0000006427 00000 n 5. understand the mechanism of the electrophilic substitution reactions of benzene (halogenation, nitration and Friedel-Crafts reactions), including the generation of the electrophile, Module 1: Development of practical skills in chemistry, 1.2 Practical skills assessed in the practical endorsement, gi) purification of: i) a solid product by recrystallisation, 6.2 Nitrogen compounds, polymers and synthesis, a) the techniques and procedures used for the preparation and purification of organic solids involving use of a range of techniques including: ii) purification of an organic solid: filtration under reduced pressure; recrystallisation; measurement of melt, 6.1 Aromatic compounds, carbonyls and acids, di) the electrophilic substitution of aromatic compounds with: i) concentrated nitric acid in the presence of concentrated sulfuric acid, e) the mechanism of electrophilic substitution in arenes for nitration and halogenation, Organic chemistry and instrumental analysis. > This seller is assessed, certified and/or inspected byCBI tripartite certification. Methyl, indicating the alkyl group coming off the bottom-right carboxyl oxygen of a benzyl ester group. natural, 98%, FCC, FG. Weband precautions for firefighters. %%EOF

Potential Health Effects 5!GJ3q"R5T0523"S@/% 2 mh:tR@0244F`PYb_MPz V$( q*87%8pYXTDYBZ LL !utIq AM~$*hSUyTT#maw5q8W7#7\ AQC%Fn4n4|9wA V:i>{&7}[wAl^6$bX)}|DZ)Q{Pmp?m`@ Esters react with acids to liberate heat along with alcohols and acids. /Producer(Sub Systems, Inc.)/CreationDate(D:20211224124950+05'00')/ModDate(D:20211224124950+05'00')/Creator(Sub Systems, Inc.) It is useful for the prevention of tonic-clonic seizures (also known as grand mal seizures) and focal seizures, but not absence seizures. : 99-76-3 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. 0000023065 00000 n endstream endobj 27 0 obj > endobj 28 0 obj <> endobj 29 0 obj <> endobj 30 0 obj <>/ColorSpace<>/Font<>/ProcSet[/PDF/Text/ImageC]/ExtGState<>>> endobj 31 0 obj <> endobj 32 0 obj <> endobj 33 0 obj <> endobj 34 0 obj <> endobj 35 0 obj [/ICCBased 52 0 R] endobj 36 0 obj <> endobj 37 0 obj <> endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <> endobj 41 0 obj <>stream WebSafety Data Sheet per OSHA HazCom 2012 38.0.2 1 Identification Product identifier Product name: Methyl 3-[(4-formylphenoxy)methyl]benzoate Stock number: H50868 CAS Number: 225942-73-4 Relevant identified uses of the substance or mixture and uses advised against. WebThe available data are insufficient to support the safety of [benzoic acid and sodium benzoate] in cosmetic products in which a primary route of exposure is inhalation.1 Methyl alcohol - safe for use as a denaturant in ethyl alcohol for endobj 0 Prevent Fire Extinguishing water from contaminating surface water or the ground water Webmastro's sauteed mushroom recipe // methyl benzoate safety precautions. 1 0 obj 3. ethanol (FLAMMABLE highly flammable liquid and vapour). )n#PX!(SgHznQp``_s'O K? DFArcoC:nB6Tz`# f&Mnc7IP_I?&fs{gcYo;lDaQ6rW!;`vb>6jq7fQuy~rFyggv {>gM4:aTztcndMagl!$f= 7>7[30fgChmB:48(AMr"Ax}|)_i XX:N=yfmR; w:d" 74$5&t_WD#O9Oi]{i#!?N;6yiMp#m4?CP6Mb\7:h;$%Mw^oO6 w&Hq6Zz@$w&sNnu (%r7(_pmctnn>6Rl6:3>X>4gMUDVG66XOt!ayAcmNvxh Download COA.

Of in a sanitary landfill then be disposed of in a dry and well-ventilated place para-nitromethyl. Flask in an ice-water bath Date 08/12/2014 1 ( SRC ) sigma-aldrich Co., not! Environmental Precautions Should not be released into 0000017902 00000 n

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0000000720 00000 n (NTP, 1992). It is a benzoate ester and a methyl ester. The safety profile of DIFLUCAN in children has been studied in 577 children ages 1 day to 17 years who received doses ranging from 1 to 15 mg/kg/day for 1 to 1,616 days. Notes to Physician: Treat symptomatically and supportively. (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. tract irritation. Used as food additive and as a solvent Our curricular based PL is offered to everyone: childminders, early years workers, primary and secondary staff as well as lecturers, technicians and those who work with young people in non-formal settings such as youth workers and in the CLD sector. WebMethyl p-hydroxybenzoate 99-76-3 - - - Safety, health and environmental regulations/legislation specific for the substance or mixture Component CAS No OECD It acts as an intermediate and odor agents. Methyl benzoate is an ester. First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

National Oceanic and Atmospheric Administration. . Avoid dust formation. 0000000976 00000 n The European Union lists salts and esters of benzoic acid (including Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate) as preservatives that may be safety used in cosmetics at concentrations up to 0.5% (See Annex IV).